摘要 : The hydrosilylation of aldehydes and ketones under mild conditions with hydrido thiophenolato iron(II) complexes [cis-Fe(H)(SAr)(PMe3)(4)] (1-4) as catalysts is reported using (EtO)(3)SiH as an efficient reducing agent in the yiel... 展开 The hydrosilylation of aldehydes and ketones under mild conditions with hydrido thiophenolato iron(II) complexes [cis-Fe(H)(SAr)(PMe3)(4)] (1-4) as catalysts is reported using (EtO)(3)SiH as an efficient reducing agent in the yields up to 95%. Among them complex 1 is the best catalyst. Complex 1 could also be used as catalyst to reduce the alpha,beta-unsaturated carbonyl compounds selectively to the alpha,beta-unsaturatedalcohols in high yields. (C) 2017 Published by Elsevier B.V. 收起