摘要 : The reductive dehydration of amides to nitriles under hydrosilation conditions with hydrido thiophenolato iron(II) complexes [cis-Fe(H)(SAr)(PMe3)(4)] (1-4) as catalysts is reported using (EtO)(3)SiH as an efficient reducing agent... 展开 The reductive dehydration of amides to nitriles under hydrosilation conditions with hydrido thiophenolato iron(II) complexes [cis-Fe(H)(SAr)(PMe3)(4)] (1-4) as catalysts is reported using (EtO)(3)SiH as an efficient reducing agent in the yields up to 93%. The merits of this catalytic system, the low catalyst loadings (2 mol%) and the amount of efficient reducing agent (EtO)(3)SiH, make this method more attractive. (C) 2016 Elsevier B.V. All rights reserved. 收起