摘要 : A highly efficient iodine anion catalyzed cross-dehydrogenativearomatization of cyclohexenones with amines has been developed undermetal-free conditions, which affords aromatic amines in good to excellentyields with a broad substr... 展开 A highly efficient iodine anion catalyzed cross-dehydrogenativearomatization of cyclohexenones with amines has been developed undermetal-free conditions, which affords aromatic amines in good to excellentyields with a broad substrate scope. Meanwhile, this reaction providesa new method for the construction of C(sp(2))-N bondsand also a new strategy for slow generation of oxidants or electrophilesvia in situ dehalogenation. Moreover, this protocol affords a rapidand concise approach to chiral NOBIN derivatives. 收起