摘要 : The chlorobridged complexes [Cp*MCl2](2) (Cp* = C5Me5, M = Ir, Rh), [(p-cymene)RuCI2](2), [(C6Me6)RuCl2](2), and [(PEt3)PdCl2](2) react with SAMP by cleavage of the chloro bridges to give the corresponding monomeric eta 1-SAMP com... 展开 The chlorobridged complexes [Cp*MCl2](2) (Cp* = C5Me5, M = Ir, Rh), [(p-cymene)RuCI2](2), [(C6Me6)RuCl2](2), and [(PEt3)PdCl2](2) react with SAMP by cleavage of the chloro bridges to give the corresponding monomeric eta 1-SAMP complexes. The X-ray structural determinations of Cp*RhCl2NH2N(CH(CH2OCH3)(CH2)(3)) and [(C6Me6)RuCl2NH2N(CH(CH2OCH3)(CH2)(3))] show coordination of the amino group in these complexes. From the chloro-bridged complexes, SAMP and sodium alpha-ketocarboxylates Schiff-base N,O-chelate complexes were obtained. The structure of the [Cp*(Cl)I rO(2)CC(CH3) = N(NCH(CH2OCH3)(CH2)(3))] coordination of the carboxylate-O and the imine-N atom was determined by X-ray diffraction. [References: 49] 收起