摘要 : Proline methylester (L-1) and proline amide (L-2) give with the chloro bridged complexes [(eta(5)-C5Me5)MCl2](2) (M = Rh, Ir), [(eta(6)-benzene)RuCl2](2) and [Et3PPdCl2](2) N and N,O coordinated compounds: (eta(5)-C5Me5)M(Cl-2)L-1... 展开 Proline methylester (L-1) and proline amide (L-2) give with the chloro bridged complexes [(eta(5)-C5Me5)MCl2](2) (M = Rh, Ir), [(eta(6)-benzene)RuCl2](2) and [Et3PPdCl2](2) N and N,O coordinated compounds: (eta(5)-C5Me5)M(Cl-2)L-1 (1, 2 M = Rh, Ir), [(eta(5)-C5Me5)Rh(Cl)(L-2)]Cl-+(-) (5), [(eta(6)-C6Me6)Ru(Cl)(L-2)]Cl-+(-) (6), [(eta(6)-p-cymene)Ru(Cl)(L-2)]Cl-+(-) (7), [(eta(5)-C5Me5)M(Cl)(L-2-H+)] (9, 10 M=Rh, Ir), (Et3P)Pd(Cl)(2)L-1 (3), and [(Et3P)Pd(Cl)(L-2)]Cl-+(-) (8). The NMR spectra indicate that for 5 and 6 only one diastereoisomer is formed. The complexes 1, 2, 3 and 5 were characterized by X-ray diffraction. [References: 53] 收起