摘要 : The chloro-bridged complexes [Cp~8MCl_2]_2 (Cp~* = C_5Me_5, M = Ir, Rh), [(p-cymene)RuCl_2]_2, [(C_6Me_6)RuCl_2]_2 and [(PEt_3)PdCl_2]_2 react with SAMP by cleavage of the chloro bridges to give the corresponding monomeric #eta#~1... 展开 The chloro-bridged complexes [Cp~8MCl_2]_2 (Cp~* = C_5Me_5, M = Ir, Rh), [(p-cymene)RuCl_2]_2, [(C_6Me_6)RuCl_2]_2 and [(PEt_3)PdCl_2]_2 react with SAMP by cleavage of the chloro bridges to give the corresponding monomeric #eta#~1-SAMP complexes. The X-ray structural determinations of [Cp~*RhCl_2NH_2N(CH(CH_2OCH_3)(CH_2)_3)] and [(C_6Me_6)RuCl_2NH_2N(CH(CH_2OCH_3)(CH_2)_3)] show coordination of the amino group in these complexes. From the chloro-bridged complexes, SAMP and sodium #alpha#-ketocarboxylates Schiff-base N, O-chelate complexes were obtained. The structure of the [Cp~*(Cl)IrO_2CC(CH_3)=NN(CH(CH_2-OCH_3)(CH_2)_3)] complex with coordination of the carboxylate-O and the imine-N atom was determined by X-ray diffraction. 收起