摘要 : The oxidation of carbon catalyst supports causes acute degradation in catalyst performance in proton exchange membrane fuel cells (PEMFCs). Tungsten oxide is considered here as a candidate material as an alternative catalyst suppo... 展开 The oxidation of carbon catalyst supports causes acute degradation in catalyst performance in proton exchange membrane fuel cells (PEMFCs). Tungsten oxide is considered here as a candidate material as an alternative catalyst support. A new method has been developed that allows Pt deposition on tungsten oxide catalyst supports. The electrochemical stability of tungsten oxide was studied by applying a coating of a tungsten-oxide-supported Pt catalyst to a rotating disk electrode and to a gold mesh. Accelerated oxidation tests were performed in deoxygenated 0.5 M H2SO4 at 30 and 80 degrees C. The oxidation stability of Pt/tungsten oxide and of Hispec 4000, a commercial catalyst, each coated on a gold mesh, was measured at 80 degrees C. The oxygen reduction reaction (ORR) activity of Pt/tungsten oxide remained high, even after accelerated oxidation tests, while the ORR activity was extremely poor after accelerated oxidation tests of Hispec 4000. (c) 2007 The Electrochemical Society. 收起