摘要 : Thermogravimetry was used to study the non-isothermal decomposition kinetics and the stability of porphyrin copper-sodium from ephedra. The kinetic equation for the second step can be expressed as dα/(dT)=Ae-(Eα)/(RT)3/2(1-α)4/3/[... 展开 Thermogravimetry was used to study the non-isothermal decomposition kinetics and the stability of porphyrin copper-sodium from ephedra. The kinetic equation for the second step can be expressed as dα/(dT)=Ae-(Eα)/(RT)3/2(1-α)4/3/[(1-α)-1/3-1]. The kinetic compensation effect is found to be: lnA=0.2468Ea-8.0513. Ea is 206.61 kJ/mol. The results show that porphyrin copper-sodium has a high activation energy and good stability. 收起