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PM10 (particulate matter with aerodynamic diameter less than 10 μm) samples were collected simultaneously at nine urban sites and one urban background site during two intensive observation campaigns in 2006. Concentrations of ele...
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PM10 (particulate matter with aerodynamic diameter less than 10 μm) samples were collected simultaneously at nine urban sites and one urban background site during two intensive observation campaigns in 2006. Concentrations of elemental carbon (EC) and organic carbon (OC) in PM10 were analyzed using an element analyzer. The characteristics regarding spatial and seasonal distribution patterns of OC and EC concentrations and their contributions to PM10 mass, as well as correlation between OC and EC, were investigated in detail. The average OC and EC concentrations for urban sites were 57.5 ± 20.8 and 8.3 ± 3.9 μg/m3, respectively, both being around three times higher than those for urban background site. As a whole, EC concentrations did not show distinct seasonal variations, though OC concentrations were generally higher in autumn than in spring. For urban sites, total carbonaceous aerosol (TCA) accounted for 33.2% in spring and 35.0% in autumn of PM10 mass. The OC and EC concentrations were found significantly correlated to each other both in spring and in autumn, implying the existence of similar emission sources such as coal combustion. The OC/EC ratios generally exceeded 2.0, indicating the presence of secondary organic carbon (SOC), whose estimated concentration for urban Chongqing was 26.7 and 39.4 μg/m3, accounting for 48.9 and 61.9% of the total OC observed in the samples, in spring and in autumn,respectively.
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Campaigns were conducted to measure Organic Carbon (OC) and Elemental Carbon (EC) in PM2.5 during winter and summer 2003 in Beijing. Modest differences of PM2.5 and PM10 mean concentrations were observed between the winter and sum...
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Campaigns were conducted to measure Organic Carbon (OC) and Elemental Carbon (EC) in PM2.5 during winter and summer 2003 in Beijing. Modest differences of PM2.5 and PM10 mean concentrations were observed between the winter and summer campaigns. The mean PM2.5/PM10 ratio in both seasons was around 60%, indicating PM2.5 contributed significantly to PM10. The mean concentrations of OC and EC in PM2.5 were 11.2±7.5 and 6.0±5.0μg m-3 for the winter campaign, and 9.4±2.1 and 4.3±3.0 μg m-3 for the summer campaign, respectively. Diurnal concentrations of OC and EC in PM2.5 were found high at night and low during the daytime in winter, and characterized by an obvious minimum in the summer afternoon. The mean OC/EC ratio was 1.87±0.09 for winter and Z39±0.49 for summer. The higher OC/EC ratio in summer indicates some formation of Secondary Organic Carbon (SOC). The estimated SOC was 2.8 μg m-3 for winter and 4.2μg m-3 for summer.
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Concentrations of dissolved and particulate organic carbon (DOC and POC) were documented in 1996-1997 at 4 different trophic state stations in Donghu Lake, a typical shallow eutrophic lake along the Changjiang River's middle reach...
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Concentrations of dissolved and particulate organic carbon (DOC and POC) were documented in 1996-1997 at 4 different trophic state stations in Donghu Lake, a typical shallow eutrophic lake along the Changjiang River's middle reaches. The mean concentrations of DOC were 15.11±3.26, 15.19±4.24, 14.27±3.43, and 13.31±3.30 mg/L in Station I, II, III, and IV, respectively. The DOC concentrations of the studied area were very similar to that in other lakes along the Changjiang River's middle reaches. The POC mean of the whole lake was 5.01 mg/L due to the large amount of organic detritus of both allochthonous and autochthonous origin. Significant linear relationship was found between POC and chlorophyll a at all 4 stations, which presumably reflect that phytoplankton, its exudates and its metabolic products were the main contributors to the POC pool in the water column. The slope of such linear relationship at Station IV was significantly steeper than that at Station I, II and III. In addition, the DOC/POC ratios (mean value: 4.40) indicated that the organic detritus was the most important component of the particulate organic matter; in other words, next to organic detritus, phytoplankton dominated the particulate organic matter in Donghu Lake.
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This paper reports data on the dissolved and colloidal organic carbon in the Zhujiang (Pearl) River estuary. DOC concentration was 142 to 239 μmol/L in the freshwater taken in March 1997 from the four Zhujiang River tributaries f...
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This paper reports data on the dissolved and colloidal organic carbon in the Zhujiang (Pearl) River estuary. DOC concentration was 142 to 239 μmol/L in the freshwater taken in March 1997 from the four Zhujiang River tributaries flowing into the Lingdingyang estuary. High concentration was observed in the Humen tributary located near Guangzhou. The rapidly increased DOC concentration at low salinities (~5) may be attributed to the exchange between macroparticulate and dissolved organic matter during the early stage of estuarine mixing. DOC concentration overall followed the mixing line until salinity ~25, where the Deep Bay is located and where DOC was elevated. This elevated DOC may suggest a local organic matter source from Shenzhen. Using a cross-flow ultrafiltration (CFF) system equipped with a Millipore Prep-scale CFF 1 kD regenerated cellulose membrane, we also separated the colloidal organic matter from the truly dissolved fraction (<1 kD). CFF membranes were carefully evaluated for their applicability (retention characteristics, blank level and mass balance) to separate colloidal organic matter. COC in the study area ranged from 5 to 85 μmol/L, representing ~ 3%-32% of DOC. The highest COC percentage was found at low salinities (< 5) in both winter and summer. Evidence suggests in-situ production of colloidal material at this salinity range. Beyond this point, a very modest removal was observable until high salinities. Again, an increase in COC concentration was shown in the samples taken from the Deep Bay.
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Characterization of carbonaceous aerosols including CC(carbonate carbon),OC(organic carbon),and EC(elemental carbon)were investigated at Xi'an,China,near Asian dust source regions in spring 2002.OC varied between 8.2 and 63.7 μg ...
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Characterization of carbonaceous aerosols including CC(carbonate carbon),OC(organic carbon),and EC(elemental carbon)were investigated at Xi'an,China,near Asian dust source regions in spring 2002.OC varied between 8.2 and 63.7 μg m-3,while EC ranged between 2.4 and 17.2μm-3 during the observation period.OC variations followed a similar pattern to EC and the correlation coefficient between OC and EC is 0.89(n=31).The average percentage of total carbon(TC,sum of CC,OC,and EC)in PM2.5 during dust storm(DS)events was 13.6%,which is lower than that during non-dust storm(NDS)periods(22.7%). CC,OC,and EC accounted for 12.9%,70.7%,and 16.4%of TC during DS events,respectively.The average ratio of OC/EC was 5.0 in DS events and 3.3 in NDS periods.The OC.EC correlation(R2=O.76,n=6) was good in DS events,while it was stronger(R2=0.90,n=25)in NDS periods.The percentage of water. soluble OC(WSOC)in TC accounted for 15.7%,and varied between 13.3%and 22.3%during DS events. The distribution of eight carbon fractions indicated that local emissions such as motor vehicle exhaust were the dominant contributors to carbonaceous particles.During DS events.soil dust dominated the chemical composition,contributing 69%to the PM2.5 mass,followed by organic matter(12.8%),sulfate(4%),EC (2.2%),and chloride(1.6%).Consequently,CC was mainly entrained by Asian dust.However,even in the atmosphere near Asian dust source regions,OC and EC in atmospheric dust were controlled by local emission rather than the transport of Asian dust.
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