摘要 : Examination of different silane reducing agents in the reductive aldol reaction revealed that Me(2)i-PrSiH is highly selective for formation of the silylated aldol adduct versus the derived acylated adduct. This silicon group prov... 展开 Examination of different silane reducing agents in the reductive aldol reaction revealed that Me(2)i-PrSiH is highly selective for formation of the silylated aldol adduct versus the derived acylated adduct. This silicon group provides more robust protection for the product beta-hydroxyl group than the diethylmethylsilyl group, which was employed previously. 收起