摘要 : Metal oxide carbon nanotube ((NT) composite microspheres with a novel structure were fabricated using a one-step spray pyrolysis process. Metal oxide CNT composite microspheres with a uniform distribution of void nanospheres were ... 展开 Metal oxide carbon nanotube ((NT) composite microspheres with a novel structure were fabricated using a one-step spray pyrolysis process. Metal oxide CNT composite microspheres with a uniform distribution of void nanospheres were prepared from a colloidal spray solution containing CNTs, metal salts, and polystyrene (PS) nanobeads. Perforated SnO2 (NT composite microspheres with a uniform distribution of void nanospheres showed excellent lithium storage properties as anode materials for lithium-ion batteries. Bare SnO2 microspheres and SnO2 (NT composite microspheres with perforated and filled structures had a discharge capacity of 450, 1108, and 590 mA h g(-1) for the 250th cycle at a current density of 1.5 A g(-1), and the corresponding capacity retention compared to the second cycle was 41, 98, and 55%, respectively. The synergetic combination of void nanospheres and flexible CNTs improved the electrochemical properties of SnO2. This effective and innovative strategy could be used for the preparation of perforated metal oxide-CNT composites with complex elemental compositions for many applications. 收起