摘要 : In order to improve the encapsulation of metal ions coordinated by tris(thioimidazolyl)borate ligands,four new such ligands with o-substituted phenyl substituents were synthe-sised as well as ones with p-tolyl and cyclohexyl subst... 展开 In order to improve the encapsulation of metal ions coordinated by tris(thioimidazolyl)borate ligands,four new such ligands with o-substituted phenyl substituents were synthe-sised as well as ones with p-tolyl and cyclohexyl substituents.In order to provide a basis for their bioinorganic zinc complex chemistry,they were converted to some zinc-halide,-carbox-ylate,-nitrate,-phenolate and -benzylate complexes.They form zinc-perchlorate complexes which are productive starting materials for the attachment of alcohols and alkoxides at zinc,thereby yielding new structural models for the zinc enzyme alcohol dehydrogenase. 收起