摘要 : A novel and direct synthesis of hydroperoxy compounds from various types of conjugated olefins was established via cobalt(II) porphyrin-catalyzed hydroperoxygenation. The reaction of alpha,beta,gamma,delta-unsaturated carbonyl com... 展开 A novel and direct synthesis of hydroperoxy compounds from various types of conjugated olefins was established via cobalt(II) porphyrin-catalyzed hydroperoxygenation. The reaction of alpha,beta,gamma,delta-unsaturated carbonyl compounds, acrylic esters, alpha-substituted acrylic esters and styrene derivatives with molecular oxygen and triethylsilane in the presence of a catalytic amount of cobalt(II) porphyrin proceeded rapidly to give the corresponding hydroperoxygenated compounds in high or moderate yields. [References: 45] 收起