摘要 : <abstract type="main" xml:lang="en"> <title type="main">Abstract</title> <p> The Monte Carlo simulation method proposed in Part 1 of this series is used to investigate the branched architecture of hyperbran... 展开 <abstract type="main" xml:lang="en"> <title type="main">Abstract</title> <p> The Monte Carlo simulation method proposed in Part 1 of this series is used to investigate the branched architecture of hyperbranched polymers formed through self‐condensing vinyl polymerization (SCVP) in a continuous stirred‐tank reactor (CSTR). The degree of branching (DB) at large chain length ( <i>P</i> ) limit, DB _inf , does not change with the mean residence time <mat:math display="inline" altimg="urn:x-wiley:dummy:media:mats201800028:mats201800028-math-0001" wiley:location="equation/mats201800028-math-0001.png"> <mat:mover accent="true"> <mat:mi>t</mat:mi> <mat:mo>ˉ</mat:mo> </mat:mover> </mat:math> . The value of DB _inf is larger than the corresponding batch polymerization. The relationship between the mean‐square radius of gyration &lt; <i>s</i> ² &gt; ₀ and <i>P</i> does not change with <mat:math display="inline" altimg="urn:x-wiley:dummy:media:mats201800028:mats201800028-math-0002" wiley:location="equation/mats201800028-math-0002.png"> <mat:mover accent="true"> <mat:mi>t</mat:mi> <mat:mo>ˉ</mat:mo> </mat:mover> </mat:math> , and high molecular weight (MW) polymers obtained in a CSTR are much more compact than those formed in batch polymerization. At least for the high MW polymers, CSTR is advantageous to synthesize compact hyperbranched polymers. </p> </abstract> 收起