摘要 : The preparation of two homoleptic manganese(II)complexes [Mn(4'R-ind)2] [ind is the anion of 1,3-bis(2-pyridylimino)isoindoline,R = H(1),Me(2)] is described.Both complexes have been structurally characterized by UV-Vis and IR spec... 展开 The preparation of two homoleptic manganese(II)complexes [Mn(4'R-ind)2] [ind is the anion of 1,3-bis(2-pyridylimino)isoindoline,R = H(1),Me(2)] is described.Both complexes have been structurally characterized by UV-Vis and IR spectroscopies.Crystallographic characterization of the [Mn(ind)2](1)complex has shown that the overall geometry around the six-coordinate manganese(II)ion is described as a slightly distorted octahedron in an N6 donor set.These complexes represent functional model systems for manganese catalases. 收起