摘要 : Ceric ammonium nitrate (3 mol%) efficiently catalyzes the aza-Michael reaction of amines with alpha,beta-unsaturated carboryl compounds in water to produce the corresponding beta-amino carbonyl compounds in good to excellent yield... 展开 Ceric ammonium nitrate (3 mol%) efficiently catalyzes the aza-Michael reaction of amines with alpha,beta-unsaturated carboryl compounds in water to produce the corresponding beta-amino carbonyl compounds in good to excellent yields (55-99%) for most of the compounds under mild conditions. The reaction is procedurally simple and displays limited chemoselectivity, as aromatic amines were found to be unreactive. 收起