摘要 : In this work it was demonstrated that the sodium and potassium salts of a sandwich-type tetra-cobalt tungstophosphate, [Co-4(H2O)(2)(PW9O34)(2)](10-), are efficient catalysts for the selective oxidation of alcohols into correspond... 展开 In this work it was demonstrated that the sodium and potassium salts of a sandwich-type tetra-cobalt tungstophosphate, [Co-4(H2O)(2)(PW9O34)(2)](10-), are efficient catalysts for the selective oxidation of alcohols into corresponding aldehydes with hydrogen peroxide in water. Among these two salts, Na-10[Co-4(H2O)(2)(PW9O34)(2)]center dot 27H(2)O complex showed better catalytic activity for the alcohols' oxidation. Using trace amounts of catalyst, different benzylic and aliphatic hydroxyl groups were converted into the corresponding carbonyl compounds in high to excellent yields. 收起