摘要 : Enolate of Wieland-Miescher ketone 1 has reacted with methyl acrylate to give methyl (1S*,2S*,4R*,6S*)-6-methyltricyclo[6.2.2(1,6)]-dodecan-7,12-dion-2-carboxy late 5 whose structure has been determined by Xray crystallography aft... 展开 Enolate of Wieland-Miescher ketone 1 has reacted with methyl acrylate to give methyl (1S*,2S*,4R*,6S*)-6-methyltricyclo[6.2.2(1,6)]-dodecan-7,12-dion-2-carboxy late 5 whose structure has been determined by Xray crystallography after transformation of 5 into sultamamide 8a. [References: 12] 收起