摘要 : Various methylarenes are treated with 1,3-dibromo-5,5-dimethylhydantoin or N-bromosuccinimide and a catalytic amount of 2,2'-azobis(isobutyronitrile) in acetonitrile, carbon tetrachloride, or methyl tert-butyl ether, and then reac... 展开 Various methylarenes are treated with 1,3-dibromo-5,5-dimethylhydantoin or N-bromosuccinimide and a catalytic amount of 2,2'-azobis(isobutyronitrile) in acetonitrile, carbon tetrachloride, or methyl tert-butyl ether, and then reacted with benzoic acid, p-toluenethiol, sodium p-toluenesulfinate, aqueous dimethylamine, and succinimide (formed from N-bromosuccinimide) to provide the corresponding arylmethyl benzoates, arylmethyl p-tolyl thioethers, arylmethyl p-tolyl sulfones, N-arylmethyl-N, N-dimethylamines, and N-(arylmethyl) succinimides in good yields, respectively. The reactions involve one-pot, transition-metal-free functionalizations to form C-O, C-S or C-N bonds at the benzylic positions of the methylarenes. 收起