摘要 : Adducts from Organometallic Lewis Acids [Fe(CO)(2)Cp](+), [Fe(CO)(PPh3)Cp](+), [Ru(PPh3)(2)Cp](+), [Re(CO)(5)](+), [1/2 Pt(PPh3)(2)](+), [W(CO)(3)Cp](+) and the anionic thiocarbonyl complexes [HB(pz)(3)(OC)(2)M(CS)(-) (M = Mo, W) ... 展开 Adducts from Organometallic Lewis Acids [Fe(CO)(2)Cp](+), [Fe(CO)(PPh3)Cp](+), [Ru(PPh3)(2)Cp](+), [Re(CO)(5)](+), [1/2 Pt(PPh3)(2)](+), [W(CO)(3)Cp](+) and the anionic thiocarbonyl complexes [HB(pz)(3)(OC)(2)M(CS)(-) (M = Mo, W) have been prepared. Their spectroscopic data indicate that the addition of the cations occurs at the sulphur atom to give end-to-end thiocarbonyl bridged complexes [HB(pz)(3)(OC)(2)MCSM'L-n]. 收起