《Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry》 2004年15卷9期
摘要
:
alpha,alpha'-Bis(trifluoromethyl)-9,10-anthracenedimethanol was prepared by a one pot stereoselective doable reduction in good yield and excellent enantiomeric excess. We examined the association with ortho- and meta-benzenedimeth...
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alpha,alpha'-Bis(trifluoromethyl)-9,10-anthracenedimethanol was prepared by a one pot stereoselective doable reduction in good yield and excellent enantiomeric excess. We examined the association with ortho- and meta-benzenedimethanol showing bidentate complexes stable enough to be studied by low temperature NMR. Molecular modeling helped us to propose an association complex. (C) 2004 Elsevier Ltd. All rights reserved.
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