摘要 : VO(acac)_2 catalyzes the oxidation of aldehydes (aromatic, aliphatic, and heterocyclic) to the corresponding acids efficiently and selectively in the presence of H_2O_2 as an oxidant. This method possesses functional-group compati... 展开 VO(acac)_2 catalyzes the oxidation of aldehydes (aromatic, aliphatic, and heterocyclic) to the corresponding acids efficiently and selectively in the presence of H_2O_2 as an oxidant. This method possesses functional-group compatibility, easy workup procedure, and shorter reaction time. The reaction is highly dependent on the solvent used. Performance of titania-supported VO(acac)_2 in the oxidation of aldehyde was also investigated. 收起