摘要 : It is no longer necessary to use dialkylzinc reagents to obtain enantioselectivities >95% in the copper-catalyzed asymmetric conjugate addition of organometallic compounds to cyclic enones. We now report how this can be accomplish... 展开
作者 | Feringa BL Badorrey R Pena D Harutyunyan SR Minnaard AJ |
---|---|
作者单位 | |
期刊名称 | 《Proceedings of the National Academy of Sciences of the United States of America》 |
页码/总页数 | p.5834-5838 / 5 |
语种/中图分类号 | 英语 / N |
关键词 | Alpha beta-unsaturated carbonyl-compounds Highly enantioselective hydrogenation Michael additions Organic-synthesis Ligands Complexes 1 4-addition Efficient Phosphine Organocopper |
馆藏号 | N-036 |